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Properties of substance:
diethyl ether
skc-file
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
4
H
1
0
O
Structural formula as text:
C2H5OC2H5
Molar/atomic mass: 74.12199
Melting point (°C):
-116.3
Boiling point (°C):
35.6
Solubility (g/100 g of solvent):
1,1,2-trichloro-1,2,2-trifluoroethane
: miscible [
Ref.
]
acetone
: very soluble [
Ref.
]
ammonia liquid
: miscible [
Ref.
]
benzene
: miscible [
Ref.
]
chloroform
: miscible [
Ref.
]
diethylene glycol
: 19.5 (25°C) [
Ref.
]
ethanol
: miscible [
Ref.
]
ethylene glycol
: 8.5 (25°C) [
Ref.
]
glycerol 99.04%
: 0.65 (20°C) [
Ref.
]
hydrogen chloride liquid anhydrous
: soluble [
Ref.
]
hydrogen fluoride
: very soluble [
Ref.
]
ligroin: very soluble [
Ref.
]
oxygen liquid
: 0.0009 (-183°C) [
Ref.
]
sulfuric acid
: soluble [
Ref.
]
water
: 10.45 (0°C) [
Ref.
]
water
: 9.92 (7.5°C) [
Ref.
]
water
: 8.291 (10°C) [
Ref.
]
water
: 6.5 (20°C) [
Ref.
]
water
: 5.069 (30°C) [
Ref.
]
water
: 2.9 (72°C) [
Ref.
]
water
: 2.7 (82°C) [
Ref.
]
Numerical data:
Polarizability of molecules (nm
3
): 0.01
Density:
0.7362 (0°C, g/cm
3
)
0.7248 (10°C, g/cm
3
)
0.7135 (20°C, g/cm
3
)
0.70778 (25°C, g/cm
3
)
0.7019 (30°C, g/cm
3
)
Reactions:
[
Ref.1
]
(C
2
H
5
)
2
O + 4Cl
2
→ 4C + 8HCl + H
2
O
[
Ref.1
]
NOHSO
4
+ (C
2
H
5
)
2
O → C
2
H
5
OSO
3
H + C
2
H
5
ONO
Refractive index (n
D
):
1.3526 (20°C)
Vapour pressure (Torr):
1 (-74.3°C)
10 (-48.1°C)
40 (-27.7°C)
200 (2.2°C)
400 (17°C)
Dissociation:
pK
BH
+
(1) = -3.59 (20°C, water)
Permittivity (dielectric constant):
4.3 (25°C)
Dipole moment (D):
1.15 (20°C)
Viscosity (mPa·s):
0.242 (20°C)
Surface tension (mN/m):
17.01 (20°C)
Speed sound (m/s):
206.5 (97.1°C, aggregative state - gas)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-279.5 (l)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
172.4 (l)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
175.6 (l)
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
26.6
Flash point (°C):
-41
Autoignition temperature (°C):
164
Heat of combustion (kJ/mol):
2726.7
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-252.1 (g)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
342.7 (g)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
119.5 (g)
LD
50
(mg/kg):
1760 (white mice, oral)
Critical temperature (°C):
193.4
Critical pressure (MPa):
3.61
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-27
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 271-277
Yalkowsky S.H., Yan H., Jain P. Handbook of aqueous solubility data. – 2nd ed. - CRC Press, 2010. - pp. 130-131
Альберт А., Сержент Е. Константы ионизации кислот и оснований. - М.-Л.: Химия, 1964. - pp. 138 [Russian]
Бабаян Э.А., Гаевский А.В., Бардин Е.В. Правовые аспекты оборота наркотических, психотропных, сильнодействующих, ядовитых веществ и прекурсоров. - М.: МЦФЭР, 2000. - pp. 148 [Russian]
Гурвич Я.А. Справочник молодого аппаратчика-химика. - М.: Химия, 1991. - pp. 229 [Russian]
Гутман В. Химия координационных соединений в неводных растворах. - М.: Мир, 1971. - pp. 188-190 [Russian]
Девяткин В.В., Ляхова Ю.М. Химия для любознательных, или о чем не узнаешь на уроке. - Ярославль: Академия Холдинг, 2000. - pp. 48 [Russian]
Захаров Л.Н. Техника безопасности в химических лабораториях. - Л.: Химия, 1991. - pp. 167-176 [Russian]
Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 559 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 148 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 408-409 [Russian]
Справочник химика. - 2 изд., Т.1. - Л.-М.: Химия, 1966. - pp. 554 [Russian]
Хёрд Ч.Д. Пиролиз соединений углерода. - Л.-М.: ГОНТИ РКТП СССР, 1938. - pp. 185 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 194-195 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru