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Properties of substance:

iron(II) sulfate heptahydrate

Group of substances:

inorganic

Physical appearance:

bluish green monoclinic crystals

Empirical formula (Hill's system for organic substances):

H14FeO11S

Structural formula as text:

FeSO4 * 7H2O

Molar/atomic mass: 278.01

Melting point (°C):

64

Decomposition temperature (°C):

56.8

Solubility (g/100 g of solvent):

water: 15.8 (0°C) [Ref.]
water: 20.8 (10°C) [Ref.]
water: 26.3 (20°C) [Ref.]
water: 32.8 (30°C) [Ref.]
water: 40.1 (40°C) [Ref.]
water: 48.4 (50°C) [Ref.]
water: 55.3 (63.7°C) [Ref.]
water: 43.7 (80°C) [Ref.]

Density:

1.898 (18°C, g/cm3)

Reactions of synthesis:

  1. [Ref.1, Ref.2]
    Fe + H2SO4 + 7H2O → FeSO4 * 7H2O + H2

Refractive index (nD):

1.478 (20°C)

Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

-3016 (s)

Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

-2512 (s)

Standard molar entropy S0 (298.15 K, J/(mol·K)):

409.1 (s)

Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

394.5 (s)

LD50 (mg/kg):

533 (rats, oral)

References:

  1. Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 539-541
  2. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 63 [Russian]
  3. Реми Г. Курс неорганической химии. - Т.2. - М., 1966. - pp. 299 [Russian]
  4. Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 351 [Russian]

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru