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Properties of substance:
methyl nitrite
Group of substances:
organic
Physical appearance:
gas
Empirical formula (Hill's system for organic substances):
CH
3
NO
2
Structural formula as text:
CH3ONO
Molar/atomic mass: 61.04
Melting point (°C):
-17
Boiling point (°C):
-12
Solubility (g/100 g of solvent):
diethyl ether
: soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
Reactions:
Yeild 65-68%. [
Ref.1
,
Ref.2
]
C
6
H
5
COCH
2
CH
3
+ CH
3
ONO → C
6
H
5
COC(CH
3
)=NOH + CH
3
OH
[
Ref.1
]
C
6
H
5
CH
2
CH
2
COCH
3
+ CH
3
ONO → C
6
H
5
CH
2
C(COCH
3
)=NOH + CH
3
OH
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-66.1 (g)
References:
CRC Handbook of Chemistry and Physics. - 90ed. - CRC Press, 2010. - pp. 5-20
Справочник химика. - 2 изд., Т. 2. - Л.-М.: Химия, 1964. - pp. 792-793 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru