Main page (Russian) Search in database (English)

Properties of substance:

α-chloroethyl ethyl sulfide

Group of substances:

organic

Empirical formula (Hill's system for organic substances):

C4H9ClS

Structural formula as text:

CH3CH2SCHClCH3

Synthesis 1:

Reference: Bordwell, F. G., Pitt, B. M. The Formation of α-Chloro Sulfides from Sulfides and from Sulfoxides / Journal of the American Chemical Society. - 1955. - Vol. 77, No. 3 pp. 576 [doi: 10.1021/ja01608a016]

A solution of 21.2 g. (0.20 mole) of diethyl sulfoxide in 40 ml. of methylene chloride was added during 2 hours to a heated solution of 27 g. (0.23 mole) of thionyl chloride in 30 ml. of methylene chloride. The solution was refluxed for an additional hour and distilled giving 10 g. (40%) of ?-chloroethyl ethyl sulfide, b.p. 45—48° (45 mm.).

References:


    Your requests if no data into database




    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru