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Properties of substance:

4-((methylthio)methyl)morpholine

Synonyms:

4-(måthylmercaptomethyl)morpholine
N-(måthylmercaptomethyl)morpholine

Group of substances:

organic

Empirical formula (Hill's system for organic substances):

C6H13NOS

Structural formula as text:

O(CH2CH2)2NCH2SCH3

Synthesis 1:

Reference: Bordwell, F. G., Pitt, B. M. The Formation of α-Chloro Sulfides from Sulfides and from Sulfoxides / Journal of the American Chemical Society. - 1955. - Vol. 77, No. 3 pp. 575 [doi: 10.1021/ja01608a016]

A mixture of 16.2 g. (0.168 mole) of chloromethyl methyl sulfide and 35 g. (0.4 mole) of morpholine in 100 ml. of benzene was allowed to stand for 16 hours. The mixture was then added to a solution of 30 g. of potassium hydroxide in 300 ml. of water and ice. The benzene layer was separated and combined with a hexane wash. After drying over anhydrous potassium carbonate, distillation gave 15 g. (61%) of N-(methylmercaptomethyl)-morpholine, b.p. 94-100° (14 mm.).

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    © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru