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Properties of substance:

carbon tetrachloride

Synonyms:

carbon tetrachloride
tetrachloromethane

Group of substances:

organic

Physical appearance:

colorless liquid

Empirical formula (Hill's system for organic substances):

CCl4

Structural formula as text:

CCl4

CAS No: 56-23-5

Molar/atomic mass: 153.82

Melting point (°C):

-22.87

Boiling point (°C):

76.75

Decomposition temperature (°C):

400

Solubility (g/100 g of solvent):

1,1,2-trichloro-1,2,2-trifluoroethane: miscible [Ref.]
acetone: soluble [Ref.]
ammonia liquid : soluble [Ref.]
benzene: miscible [Ref.]
bromine liquid: soluble [Ref.]
chlorine liquid: very soluble [Ref.]
chloroform: miscible [Ref.]
diethyl ether: miscible [Ref.]
diethylene glycol: 35.5 (25°C) [Ref.]
ethanol: miscible [Ref.]
ethanol 50%: 6.4 (20°C) [Ref.]
ethylene glycol : 6.6 (25°C) [Ref.]
formic acid: 6.95 (25°C) [Ref.]
hydrogen fluoride : slightly soluble [Ref.]
phosphorus(V) trichloride oxide: soluble [Ref.]
propylene glycol: 30.5 (25°C) [Ref.]
sulfolane: miscible [Ref.]
water: 0.097 (0°C) [Ref.]
water: 0.083 (10°C) [Ref.]
water: 0.08 (25°C) [Ref.]
water: 0.085 (30°C) [Ref.]

Density:

1.668 (-20°C, g/cm3)
1.63195 (0°C, g/cm3)
1.602 (15°C, g/cm3)
1.5954 (20°C, g/cm3)
1.5842 (25°C, g/cm3)
1.503 (60°C, g/cm3)
1.48 (76°C, g/cm3)

Refractive index (nD):

1.4607 (20°C)

    Permittivity (dielectric constant):

    2.238 (20°C)

    Dipole moment (D):

    0 (20°C)

    Standard molar enthalpy (heat) of formation ΔfH (298 K, kJ/mol)

    -132,842 (l) [Ref.]
    -100,416 (g) [Ref.]

    Standard molar Gibbs energy of formation ΔfG (298 K, kJ/mol)

    -62,542 (l) [Ref.]
    -58,154 (g) [Ref.]

    Standard molar entropy S (298 K, J/(mol·K))

    216,187 (l) [Ref.]
    310,228 (g) [Ref.]

    Molar heat capacity at constant pressure Cp (298 K, J/(mol·K))

    133,888 (l) [Ref.]
    83,404 (g) [Ref.]

    Enthalpy (heat) of fusion ΔfusH (kJ/mol)

    2,56 (s) [Ref.]

    Enthalpy (heat) of vaporization at boiling point ΔvapH (kJ/mol)

    29,82 (l) [Ref.]

    Enthalpy (heat) of vaporization ΔvapH (kJ/mol)

    32,43 (l) [25°C] [Ref.]

    Critical temperature (°C):

    283.2

    Critical pressure (MPa):

    4.5

    References:

    1. Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 214-216
    2. Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 2-6
    3. Yalkowsky S.H., Yan H. Handbook of aqueous solubility data. - CRC Press, 2003. - pp. 17-18
    4. Альберт А. Избирательная токсичность. - Т.2. - М.: Медицина, 1989. - pp. 308 [Russian]
    5. Гордон А., Форд Р. Спутник химика. - М.: Мир, 1976. - pp. 187 [Russian]
    6. Некрасов Б.В. Основы общей химии. - Т.1. - М.: Химия, 1973. - pp. 529 [Russian]
    7. Промышленные хлорорганические продукты: Справочник. - М.: Химия, 1978. - pp. 35-44 [Russian]
    8. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 185-186 [Russian]
    9. Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 369 [Russian]
    10. Справочник по растворимости. - Т.1, Кн.2. - М.-Л.: ИАН СССР, 1962. - pp. 1021-1041 [Russian]
    11. Успехи химии. - 1971. - Т.40, №2. - pp. 226-253 [Russian]
    12. Успехи химии. - 1971. - Т.40, №3. - pp. 462-490 [Russian]
    13. Успехи химии. - 1989. - Т.58, №1. - pp. 146 [Russian]
    14. Химическая энциклопедия. - Т. 5. - М.: Советская энциклопедия, 1999. - pp. 392-393 [Russian]
    15. Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 688 [Russian]
    16. Химия и жизнь. - 1990. - №5. - pp. 82 [Russian]
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      © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru