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Properties of substance:

titanium(IV) bromide


Physical appearance:

yellow cubic crystals

Empirical formula (Hill's system):

Br4Ti

Structural formula:

TiBr4

Molar/atomic mass: 367.52

Melting point (°C):

38

Boiling point (°C):

231

Solubility (g/100 g of solvent):

water: reaction [Ref.]
diethyl ether: soluble [Ref.]
carbon tetrachloride: soluble [Ref.]
ethanol: soluble [Ref.]

Gigroscopic:

very gigroscopic

Density:

3.24 (20°C, g/cm3)

    Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

    -619.2 (s)

    Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

    -592 (s)

    Standard molar entropy S0 (298.15 K, J/mol·K):

    243.5 (s)

    Molar heat capacity at constant pressure Cp (298.15 K, J/mol·K):

    131.5 (s)

    Molar enthalpy (heat) of fusion ΔfusH (kJ/mol):

    12.9

    Enthalpy (heat) of vaporization ΔvapH (kJ/mol):

    44.4

    References:

    1. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 104
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      © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru