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Properties of substance:

tin(IV) chloride

Synonyms:

tin tetrachloride
stannic chloride

Group of substances:

inorganic

Physical appearance:

colorless fuming liquid

Empirical formula (Hill's system for organic substances):

Cl4Sn

Structural formula as text:

SnCl4

Molar/atomic mass: 260.522

Melting point (°C):

-33

Boiling point (°C):

112

Solubility (g/100 g of solvent):

acetone: soluble [Ref.]
arsenic trichloride: very soluble [Ref.]
benzene: miscible [Ref.]
benzine: soluble [Ref.]
carbon disulphide: miscible [Ref.]
carbon tetrachloride: soluble [Ref.]
diethyl ether: reaction [Ref.]
dimethylsulfoxide: soluble [Ref.]
ethanol: reaction [Ref.]
ethyl acetate: soluble [Ref.]
ethylene glycol : soluble [Ref.]
kerosene: soluble [Ref.]
methanol: soluble [Ref.]
phosphorus(V) trichloride oxide: sparingly soluble [Ref.]
propylene carbonate: 26.7 (25°C) [Ref.]
pyridine: soluble [Ref.]
selenium(IV) oxychloride: 15.93 (25°C) [Ref.]
toluene: soluble [Ref.]
water: reaction [Ref.]

Density:

2.23 (20°C, g/cm3)

    Permittivity (dielectric constant):

    3.2 (22°C)

    Dipole moment (D):

    0 (20°C)

    Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

    -528.9 (l)

    Standard molar Gibbs energy of formation ΔfG0 (298.15 K, kJ/mol):

    -457.7 (l)

    Standard molar entropy S0 (298.15 K, J/(mol·K)):

    299.6 (l)

    Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

    165.3 (l)

    Molar enthalpy (heat) of fusion ΔfusH (kJ/mol):

    9.2

    Enthalpy (heat) of vaporization ΔvapH (kJ/mol):

    36.65

    Standard molar enthalpy (heat) of formation ΔfH0 (298.15 K, kJ/mol):

    -489.1 (g)

    Standard molar entropy S0 (298.15 K, J/(mol·K)):

    365 (g)

    Molar heat capacity at constant pressure Cp (298.15 K, J/(mol·K)):

    98.3 (g)

    Critical temperature (°C):

    318.7

    Critical pressure (MPa):

    3.75

    Critical density (g/cm3):

    0.742

    References:

    1. Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 1491-1492
    2. Гринвуд Н., Эрншо А. Химия элементов. - Т.1. - М.: БИНОМ. Лаборатория знаний, 2008. - pp. 362 [Russian]
    3. Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 89 [Russian]
    4. Спицын В.И., Мартыненко Л.И. Неорганическая химия. - Ч.2. - М.: ИМУ, 1994. - pp. 397 [Russian]
    5. Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 882-886 [Russian]
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      © Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru