Типы реакций (взято с Orgsyn.Org)

Категория: АЛКИЛИРОВАНИЕ, C-АЛКИЛИРОВАНИЕ (Включая реакцию Фриделя-Крафтса)

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Продукт реакции   Методика
синтеза
(3R)-3,7-Dimethyl-2-(2-oxobutyl)-6-octenal   80, 195
8-[2-(Triethoxysilyl)ethyl-1-tetralone   80, 104
methyl 5,5-dimethyl-4-oxo-hexanoate   79, 146
(1'R)-Phenyl-(2'S)-[(phenylmethyl)[(2,4,6-trimethylphenyl)sulfonyl]amino]-propyl (3R)-hydroxy-(2R),4-dimethylpentanoate   79, 116
1-Phenyl-3-butyn-1-ol   79, 27
(Z)-4-(2-PROPENYL)-3-OCTEN-1-OL   79, 11
Diethyl [2-13C]malonate   78, 113
9-Ethyl-3,6-dimethylcarbazole   77, 153
[1S(R),2S]-N-(2-Hydroxy-1-methyl-2-phenylethyl)-N,2-dimethylbenzene-propionamide, [(1S,2S)-pseudoephedrine-(R)-2-methylhydro- cinnamamide]   77, 22
5-Phenyldipyrromethane   76, 287
5,15-Diphenylporphyrin   76, 287
2-Benzyl-6-methylcyclohexanone   76, 239
6-Chloro-1-hexene   76, 221
8-Chloro-1-octene   76, 221
2-Phenylpropionic acid   76, 169
(R,R)-(-)-Pseudoephedrine L-allylglycinamide   76, 57
3-Cyclopentene-1,1-dicarboxylic acid   75, 195
6,7-Dihydrocyclopenta-1,3-dioxin-5(4H)-one   75, 189
(4R,5S)-4-Hydroxymethyl-(5-O-tert-butyldimethylsiloxymethyl)furan-2(5H)-one   75, 139
4-(2-Bromo-2-propenyl)-4-methyl-?-butyrolactone   75, 129
(3R*,4R*)- and (3R*,4S*)-4-Isopropyl-4-methyl-3-octyl-2-oxetanone   75, 116
3,3-Dimethyl-1-oxaspiro[3.5]nonan-2-one   75, 116
(±)-3-Ethyl-1-oxaspiro[3.5]nonan-2-one   75, 116
Methyl 3-hydroxy-2-methylenebutanoate   75, 106
(S)-1-(Phenylmethoxy)-4-penten-2-ol   75, 12
Ubiquinone-1   IX, 741
Tetrahydro-2-(phenylethynyl)-2H-pyran   IX, 688
2-Oxo-5-methoxyspiro[5.4]decane   IX, 643
3-(1-Octen-1-yl)cyclopentanone   IX, 640
Nitroacetaldehyde diethyl acetal   IX, 636
(2R,5S)-2-tert-Butyl-5-methyl-1-aza-3-oxabicyclo[3.3.0]octan-4-one   IX, 626
(R)-(+)-2-Methyl-2-(3-oxobutyl)cyclohexanone   IX, 610
(Z)-16?-Methyl-20-trimethylsiloxy-4,17(20)-pregnadien-3-one   IX, 564
1-Menthoxy-1-butyne   IX, 533
2-Heptyl-4,5-dihydrofuran   IX, 530
tert-Butyl [1-(tert-butoxycarbonyl)-3-oxo-4-pentenyl]carbamate   IX, 526
(R)-3-Hydroxy-4-methylpentanoic acid   IX, 497
2-(1-Hydroxycyclopropyl)-2-methyl-1-tetralone   IX, 466
Ethyl 3-hydroxy-4-pentenoate   IX, 432
1-(tert-Butyldimethylsilyl)-3-ethylindole   IX, 417
1,1-Dibromopentane   IX, 404
9,9-Dimethylspiro[4.5]decan-7-one   IX, 350
2-(1,1-Dimethylpentyl)-5-methylcyclohexanone   IX, 328
3-Octyl-trans-4-isopropyl-cis-4-methyl-2-oxetanone   IX, 293
4-Nitro-3-hexanol   IX, 242
Dimethyl (E)-5-methoxycarbonyl-2-hexenedioate   IX, 82
trans-4,7,7-Tricarbomethoxy-2-phenylsulfonylbicyclo[3.3.0]oct-1-ene   IX, 82
2-(1-Ethoxycyclohexyl)-2-(trimethylsiloxy)cyclobutanone   VIII, 578
Ethyl 4-cyclohexyl-4-oxobutanoate   VIII, 578
Salsolidine   VIII, 573
2-Propyl-1-azacycloheptane   VIII, 568
(Phenylthio)nitromethane   VIII, 550
1,2,3,4,5-Pentamethylcyclopentadiene   VIII, 505
2-Methyl-5-trimethylsilyl-2-vinylpentanoic acid   VIII, 486
trans-3-Methyl-2-vinylcyclohexanone   VIII, 479
Dicarbonyl(cyclopentadienyl)(trans-3-methyl-2-vinylcyclohexanone)iron tetrafluoroborate   VIII, 479
3-Methylcyclohexanone-3-acetic acid   VIII, 467
2-(1-Methyl-2-propynyl)cyclohexanone   VIII, 460
2-Methyl-2-phenyl-4-pentenal   VIII, 451
Methyl 7-hydroxyhept-5-ynoate   VIII, 415
(S)-(+)-4-Methyl-3-heptanone   VIII, 403
3-Methyl-2(5H)-furanone   VIII, 396
(3-Methyl-2-butenyl)propanedioic acid, dimethyl ester   VIII, 381
(3-Methyl-2-butenyl)(2-propynyl)propanedioic acid, dimethyl ester   VIII, 381
2,2-Dimethylcyclohexane-1,3-dione   VIII, 312
9,10-Dihydrofulvalene   VIII, 298
Isopropylidene ?-(hexahydroazepinylidene)malonate   VIII, 263
Hexahydro-6-ethyl-3-(hydroxymethyl)-6-allyl-2-phenyl-[2S,3S,6S,8aR]-5-oxo-5H-oxazolo[3,2a]pyridine   VIII, 241
(E)-6,10-Dimethyl-5,9-undecadien-1-yne   VIII, 226
Cyclopropenone 1,3-propanediol ketal   VIII, 173
Methyl N-(2-methyl-2-butenyl)carbamate   VIII, 68
cis- and trans-1-Acetoxy-4-(dicarbomethoxymethyl)-2-cyclohexene   VIII, 5
trans-2-(2-Propenyl)cyclopentanol   VII, 501
4-Phenyl-6-hepten-2-one   VII, 443
2-tert-Pentylcyclopentanone   VII, 424
2-(2-Oxopropyl)cyclohexanone   VII, 414
Cyclopropane-1,1-dicarboxylic acid   VII, 411
Methyl 2-methyl-1-cyclohexene-1-carboxylate   VII, 351
Methyl 2,4-cyclopentadiene-1-acetate (in solution)   VII, 339
4,5-Methylenedioxybenzocyclobutene   VII, 326
2-Heptyl-2-cyclohexenone   VII, 249
?-Farnesene   VII, 245
(E)-5-Ethyl-1,4-undecadiene   VII, 236
3-Ethoxy-6-methyl-2-cyclohexen-1-one   VII, 208
2,2-Dimethyl-4-pentenal   VII, 177
N-[2,4-Bis(1,3-diphenylimidazolidin-2-yl)-5-hydroxyphenyl]acetamide   VII, 162
Diethyl (2S,3R)-(+)-3-allyl-2-hydroxysuccinate   VII, 153
3-(1-Hydroxybutyl)-1-methylpyrrole   VII, 102
2-Butylbornene   VII, 77
Tricarbonyl[2-[(2,3,4,5h)-4-methoxy-2,4-cyclohexadien-1-yl]-5,5-dimethyl-1,3-cyclohexanedione]iron   VI, 1001
2-(1-Phenylcyclopentyl)-4,4,6-trimethyl-5,6-dihydro-1,3(4H)-oxazine   VI, 905
2-Phenylbutyronitrile   VI, 897
2-Phenoxymethyl-1,4-benzoquinone   VI, 890
2-Tetradecyl-sym-trithiane   VI, 869
N-Methyl-2-phenyl-D2-tetrahydropyridine   VI, 818
2-(3-Ethyl-5-methyl-4-isoxazolylmethyl)cyclohexanone   VI, 781
N-(2-Methylbutylidene-1-d)-1,1,3,3-tetramethylbutylamine   VI, 751
4,5-Dihydro-2-[(1-phenylmethyl-2-propenyl)thio]thiazole   VI, 704
3-Ethyl-1-hexyne   VI, 595
Ethyl (E)-2-cyano-6-octenoate   VI, 586
Ethyl 4-amino-3-methylbenzoate   VI, 581
1-Ethoxy-1-butyne   VI, 564
1,1-Diphenylethane   VI, 537
2,2-Dimethyl-3-phenylpropionaldehyde   VI, 526
2,2-Dimethyl-4-phenylbutyric acid   VI, 517
Dimethyl nitrosuccinate   VI, 503
7,9-Dimethyl-cis-8-thiabicyclo[4.3.0]nonane 8,8-dioxide   VI, 482
1-Butyl-10-methyl-?1(9)-2-octalone   VI, 242
tert-Butylmalononitrile   VI, 223
2-Benzyl-2-methylcyclohexanone   VI, 121
2-Benzyl-6-methylcyclohexanone   VI, 121
1-Benzylisoquinoline   VI, 115
2-Allyl-3-methylcyclohexanone   VI, 51
2,6,6-Trimethyl-2,4-cyclohexadienone   V, 1092
1,2,3,4,5-Pentachloro-5-ethylcyclopentadiene   V, 893
?1(9)-Octalone-2   V, 869
2,4-Nonanedione   V, 848
3-Methylpentane-2,4-dione   V, 785
5-Methyl-5-hexen-2-one   V, 767
Indole-3-acetic acid   V, 654
Ethyl 2,4-diphenylbutanoate   V, 559
Diphenylpropionic acid   V, 526
1,1-Diphenylpentane   V, 523
1,6-Dioxo-8a-methyl-1,2,3,4,6,7,8a-octahydronaphthalene   V, 486
Dimesitylmethane   V, 422
Diethyl ?-ketopimelate   V, 384
m-Cymene   V, 332
2-Butyl-2-methylcyclohexanone   V, 187
p-Bromodiphenylmethane   V, 130
1-p-Bromophenyl-1-phenyl-2,2,2-trichloroethane   V, 130
Butylacetylene   V, 117
2-Benzylcyclopentanone   V, 76
2-Vinylthiophene   IV, 980
Triphenylpropionitrile   IV, 962
?,?,?-Triphenylpropionic acid   IV, 960
p-Tricyanovinyl-N,N-dimethylaniline   IV, 953
Tetraacetylethane   IV, 869
Neophyl chloride   IV, 702
1-Methylisoquinoline   IV, 641
2-Benzoyl-1-cyano-1-methyl-1,2-dihydroisoquinoline   IV, 641
9-Methylfluorene   IV, 623
1-Methyl-3-ethyloxindole   IV, 620
Hexamethylbenzene   IV, 520
3,4-Dinitro-3-hexene   IV, 372
Diethyl ?2-cyclopentenylmalonate   IV, 291
Diethyl 1,1-cyclobutanedicarboxylate   IV, 288
DL-Aspartic acid   IV, 55
Triethyl ?-phthalimidoethane-?,?,?-tricarboxylate   IV, 55
p-Aminotetraphenylmethane   IV, 47
?-Acetyl-?-chloro-?-valerolactone   IV, 10
Triphenylchloromethane   III, 841
Diethyl benzylmalonate   III, 705
DL-Phenylalanine   III, 705
?,?'-Dicyano-?-methylglutaramide   III, 591
?2-Chloroisodurene   III, 557
Diethyl sec-butylmalonate   III, 495
DL-Isoleucine   III, 495
2-Hydroxy-5-nitrobenzyl chloride   III, 468
Ethyl ?-isopropylacetoacetate   III, 405
Ethyl (1-ethylpropenyl)methyl cyanoacetate   III, 397
Cyclopropyl cyanide   III, 223
Cyclopropanecarboxylic acid   III, 221
?-Cyclohexylphenylacetonitrile   III, 219
1,1-Cyclobutanedicarboxylic acid   III, 213
2-Chloromethylthiophene   III, 197
1-Chloromethylnaphthalene   III, 195
2-Allylcyclohexanone   III, 44
Pelargonic acid   II, 474
Ethyl sec-butylmalonate   II, 416
Ethyl 1-methylthiol-3-phthalimidopropane-3,3-dicarboxylate   II, 384
Ethyl methylmalonate   II, 279
Ethyl ?-acetoglutarate   II, 262
Ethyl acetosuccinate   II, 262
Pentamethylbenzene   II, 248
Hexamethylbenzene   II, 248
Diphenylmethane   II, 232
Ethyl isopropylmalonate   II, 93
Triphenylmethane   I, 548
Propylbenzene   I, 471
1-[?-(Benzalamino)benzyl]-2-naphthol   I, 381
Ethyl butylmalonate   I, 250
Ethyl butylacetoacetate   I, 248